Product ID:SUPER-SPOT PAINT BLUE, E&I 23 24
MSDS Date:02/23/1999
FSC:8010
NIIN:00N078830
Status Code:A
MSDS Number: CJNHQ

NELSON PAINT CO OF MICHIGAN INC

KINGSFORD, MI 49802-2040
US

Emergency Phone: 800-255-3924

Info Phone: 906-774-5566

Preparer: DOYLE YODER

Cage: 17833

NELSON PAINT CO OF MICHIGAN INC

2040 KINGSFORD, MI 49802-2040 US

Telephone: 906-774-5566

Cage: 17833

METHYL ALCOHOL

CAS: 67-56-1

RTECS: PC1400000

OSHA PEL 260 MG/M3;200 PPM

ACGIH TLV: 262 MG/M3;200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

NAPHTHA, SOLVENT; (ALIPHATIC HYDROCARBONS)

CAS: 8052-41-3

RTECS: WJ8925000

OSHA PEL 2900 MG/M3;500 PPM

ACGIH TLV: 525 MG/M3;100 PPM

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE CONT: LIQ, AEROSOLS & VAPS
OF PROD ARE IRRITATING & CAN CAUSE PAIN, TEARING, REDDENING & SWELL
ACCOMPANIED BY STINGING SENSATION AND/OR FEELING LIKE THAT OF FINE
DUST IN EYES. SKIN CONT: PR LNGD/RPTD CONT CAN RSLT IN DEFAT &
DRYING OF SKIN WHICH MAY RSLT IN SKIN IRRIT & DERM(RASH). INHAL:
HDCHS, DIZZ, NAUS, DECR BLOOD PRESS, CHANGES IN HEART RATE &
CYANOSIS (CHARACT BY BLUISH DISCOLORATI ON OF SKIN & NAILS) MAY
RSLT FROM OVEREXP TO VAP/SKIN EXPOS. INGEST: THIS MATL MAY BE
HARMFUL/FATAL IF SWALLOWED. CHRONIC: RPTS HAVE ASSOC RPTD & PRLNGD
OCCUP OVEREXP TO SOLVS W/PERM BRAIN (EFTS OF OV EREXP)
Effects of Overexposure:HLTH HAZS: AND NERVOUS SYSTEM DAMAGE.
INTERNATIONAL MISUSE BY DELIBERATELY CONCENTRATING AND INHALING
THE CONTENTS MAY BE HARMFUL OR FATAL.

First Aid:EYE: IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS. GET
IMMED MED ATTN. SKIN: IMMED FLUSH W/PLENTY OF WATER. WASH W/SOAP &
WATER. REMOVE SOILED CLTHG. WASH CLTHG SEPARATELY BEFORE REUSE. GET
MED AT TN IF IRRIT DEVELOPS/PERSISTS. INHAL: REMOVE TO FRESH AIR.
IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. GET
IMMED MED ATTN. INGEST: NOTE TO PHYS: THIS PROD CNTNS METHANOL
WHICH CAN CAUS E INTOXICATION & CNS DEPRESS. METHANOL IS
METABOLIZED TO FORMIC ACID & FORMALDEHYDE. THESE METABOLITES CAN
CAUSE METABOLIC ACIDOSIS, VISUAL DISTURB & BLNDNESS. (SUPDAT)

Flash Point:=22.2C, 72.F
Lower Limits:1.0%
Upper Limits:36.0%
Extinguishing Media:ALCOHOL FOAM, CO*2, DRY CHEMICAL FOAM.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . CNTNRS
CAN BUILD UP PRESS IF EXPOSED TO HEAT(FIRE). WATER RUNOFF CAN CAUSE
ENVIRON DMG. DIKE & COLLECT WATER USED TO FIGHT FIRE. WATER SPRAY
MAY BE USED FOR COOLING CNTNRS TO PVNT POSS PRESS BUILD-UP &
AUTO-IGNIT/EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:AVOID BRTHG DUSTS & FUMES FROM BURNING
MATL. VAPS MAY FORM EXPLO MIX W/AIR. VAPS CAN TRAVEL TO SOURCE OF
IGNIT & FLASH BACK. "EMPTY" CNTNRS RETAIN PROD RESIDUE (LIQ AND/OR
VAP) AND CAN BE DANGEROUS. D O NOT PRESSURIZE, CUT, WELD, BRAZE,
SOLDER, DRILL, GRIND/EXPOSE SUCH CNTNR TO HEAT, FLAME, SPKS, STATIC
(OTHER INFO)

Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE
ALL SOURCES OF IGNIT. VENTILATE AREA. EQUIP EMPLOYEES W/APPROP PROT
EQUIP. DIKE AROUND SPILLED MATL. COVER SPILL W/ABSORB MATL & SHOVEL
W/NON-SPARKING TOOL S INTO CNTNR. REMOVE CONTAINERS TO SAFE AREA
AND SEAL. AVOID RUNOFF INTO STORM SEWERS & DITCHES WHICH LEAD TO
WATERWAYS.

Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
SUBSTANCES. WASH THOROUGHLY AFTER HANDLING. KEEP AWAY FROM HEAT,
SPARKS & FLAME. KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:DO NOT INHALE MIST OR VAPOR. KEEP OUT OF REACH OF
CHILDREN. APPLY WITH BACK TO WIND DURING OUTDOOR APPLICATION.

Respiratory Protection:NIOSH APPRVD AIR PURIFYING RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER
CERTAIN CIRCUMSTANCES WHERE AIRBORNE CONCS ARE EXPECTED TO EXCEED
EXPOSURE LIMITS. PROT PROVIDED BY NIOSH APPRVD AIR PURIFYING RESPS
IS LIMITED. USE NIOSH APPROVD POSITIVE PRESSURE AIR SUPPLIED RESP
IF THERE IS ANY POTNTL FOR UNCONTROLLED (TOX INFO)
Ventilation:LOCAL EXHAUST VENT MAY BE NECESSARY TO CONTROL ANY AIR
CONTAMINANTS TO W/IN THEIR TLVS DURING USE OF THIS PRODUCT.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEMICAL WORKERS GOGGLES & FULL LENGTH
FACESHIELD .
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WHERE
CONTACT IS LIKELY, WEAR A CHEMICAL SUIT AND RUBBER BOOTS.
Work Hygienic Practices:DO NOT WEAR CONTACT LENSES. CNTNRS OF THIS MATL
MAY BE HAZ WHEN EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES
(VAP LIQ, AND/OR SOLID), ALL HAZARD PRECS GIVEN IN DATA SHEET MUST
BE (TOX INFO)
Supplemental Safety and Health
VOCS, LBS/GAL 5.21. VOCS, GRAMS/LTR 624. FIRST AID PROC: SINCE
METABOLISM IS REQD FOR THESE TOXIC SYMPS, THEIR ONSET MAY BE
DELAYED FROM 6 TO 30 HOURS FOLLOWING INGESTION. ETHANOL COMPETES
FOR SAME ME TABOLIC PATHWAY & HAS BEEN USED TO PVNT METHANOL
METABOLISM. ETHANOL ADMIN IS INDICATED IN (OTHER INFO)

Boiling Pt:>63.9C, 147.F
B.P. Text:147-385F
Vapor Density:HVR/AIR
Spec Gravity:1.0372
VOC Grams/Liter:5.21
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Solubility in Water:PARTIAL
Appearance and Odor:BLUE LIQUID, SLIGHT SOLVENT ODOR.
Percent Volatiles by Volume:85.3

Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH: STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAMES.
Hazardous Decomposition Products:HAZARDOUS DECOMPOSITION PRODUCTS: CO,
CO*2 AND NO*X.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL LAWS. DO NOT DISCHARGE INTO WATERWAYS WITHOUT PROPER
AUTHORITY.

Toxicological Information:RESP PROT: RELEASE, EXPOSURE LEVELS ARE NOT
KNOWN/ANY OTHER CIRCUMSTANCES WHERE NIOSH APPRVD AIR PURIFYING
RESPS MAY NOT PROVIDE ADEQ PROTECTION. HYGIENE PRACT: OBSERVED.
WASH HANDS BEFORE EATING OR S MOKING. REMOVE CONTAMD CLTHG & WASH
BEFORE REUSE. USE ONLY IN WELL VENTD AREA. GROUND & BOND CNTNRS
WHEN TRANSFERRING MATL. USE SPARK-PROOF TOOLS & EXPLO PROOF EQUIP.
AVOID PRLNGD/RPTD CONT W/SKIN. AV OID BRTHG VAPS FROM HEATED MATL.
AVOID CONT W/EYES, SKIN, & CLTHG. HMIS RATINGS: HEALTH:2,
FLAMMABILITY: 3, REACTIVITY: 1.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

SARA Title III Information:THIS PRODUCT CONTAINS FOLLOWING SUBSTANCES
SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF
SUPERFUND AMENDMENTS & REAUTHORIZATION ACT OF 1986 & 40 CFR PART
372: CHEMICAL NAME: METHYL ALCOHOL. CAS NUMBER: 67-56-1. WT/WT %
IS LESS THAN: 15%.